There are two critical hits you can land with a ranged weapon in Nightingale: a Head Shot, and a Heart Shot. Both deal significant damage to the enemy. You'll receive an early quest that asks you to hit Heartshots, but this isn't that easy - especially with your basic Slingbow.

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First, we recommend that you hold out on this quest until you unlock your first firearm as this makes hitting Heartshots signifcantly easier. Your first weapon will likely be the Lancaster Pistol, unlocked via Essence Traders for Essence Dust.
How To Land A Heartshot
Rather than a rather obvious hitbox like a headshot, the Heartshot is a much rarer hit. You should ai🐟m for where you imagine the heart t𓆏o be in the creature you're facing. Essentially in their chest, underneath the neck.
This is easiest with the wild animals you've seen on your adventures across the Realms, like Wolves, Deers, and Boars.
This is much easier with the pistol as you have multiple shots rather than the slow-to-reload Slingbow. It's a good idea to just ignore this quest for now - or land a lucky shot🐼 here 🌳or there.
The quest to land Heartshots doesn't lock anything too major behind it, so you can wait until you've crafted your first gun. The Lancaster Pistol will be unlocked in your first Tier 1 area. Nꦜightingale naturally pushes you towarℱds this with its gear score progression.
Once you've acquired the recipe and required Workbench you can begin the pretty hefty journey of crafting the gun, as it requires plenty of metal parts.
You'll also need to craft Revolver Cartridges with Ingots and Gunpowder.

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